-
Properties of optical excitations in bulk systems and
nanostructures influenced by various kinds of geometrical and
compositional disorder.
Methods: Analytical calculations and computer simulations.
The first appropriate theoretical treatment of excitons
influenced by disorder has been suggested in the paper
S.D. Baranovskii and A.L. Efros
"Band Edge Smearing in Solid Solutions",
Sov. Phys. Semicond. 12, 1328 (1978), that has received
more than 100 citations in the scientific literature.
Further studies in this field were carried out including those on
the quantitative characterization of nanostructures.
Numerous invited talks were given at conferences and
seminars, for example, "Temperature-Dependent Exciton
Luminescnece in Quantum Wells" at
"10th International Workshop of Condensed
Matter Physics", September 1998, Varna, Bulgaria.
Selected papers:
-
A.G.Abdukadirov, S.D. Baranovskii et al.
"Photoluminescence and Tunneling Relaxation of Localized
Excitons in AIIBVI Anion Mixed
Crystals", Sov. Phys. JETP 71, 1155 (1990).
-
H. Kalt, ..., S.D. Baranovskii et al. "Optical- and
Acoustic-Phonon Assisted Hopping of Localized Excitons in
CdTe/ZnTe Quantum Wells", Phys. Rev. B 45, 4253 (1992).
-
U.Siegner, ..., S.D. Baranovskii et al. "Optical Dephasing
in Semiconductor Mixed Crystals", Phys. Rev. B 46, 4564
(1992).
-
C. Klingshirn, ..., S.D. Baranovskii et al. "Dynamics of
Localized Excitons and High-Excitation Effects in II-VI Quantum
Wells and Heterostructures", Physica B 191, 90 (1993).
-
S.D. Baranovskii et al. "Exciton Line Broadening by
Compositional Disorder in Alloy Quantum Wells"
Phys. Rev. B 48, 17149 (1993).
-
A.N. Reznitsky, S.D. Baranovskii et al. "Recombination
of Aloy-Trapped Excitons in Ternary Solid Solutions with
Common Cation Components", Physica Status Solidi (b)
184, 159 (1994).
-
S.D. Baranovskii et al. "Exciton Line Broadening by
Compositional Disorder in
ZnSexTe1-x Quantum Wells",
Solid State Communications 89, 5 (1994).
-
S.Yu. Verbin, S.D. Baranovskii et al. "New Luminescence
Band in II-VI Semiconductor Crystals with treated
Surfaces", Mater. Sc. Forum 182-184, 279 (1995).
-
J.E. Colub, S.D. Baranovskii, P.Thomas "Evidence for
Dipole-Dipole Hopping of GaAs Quantum Well Excitons",
Phys. Rev. Lett. 78, 4261 (1997).
-
S.D. Baranovskii et al. "Temperature-Dependent Exciton
Luminescence in Quantum Wells: Computer Simulation",
Phys. Rev. B 58, 13081 (1998).
-
S.D. Baranovskii and T. Faber "Transport Energy for
Foerster Processes", Physica Status Solidi (b) 218, 59
(2000).
-
S.A. Tarasenko, ..., S.D. Baranovskii et al. "Energy
Relaxation of Localized Excitons at Finite Temperature",
Semicond. Sci. Technol. 16, 486 (2001).
- Influence of multi-particle electron-electron interactions
on thermodynamic, optical and transport properties of disordered
systems with localized electrons.
Methods: analytical calculations and computer simulations.
Among other results, one can emphasize the first simulation proof of
the Coulomb gap and the quantitative theory of the line shape in the
photothermal magnetospectroscopy of semiconductors. The latter theory
provides a basis for quantitative characterization of pure materials.
Numerous invited talks were given at conferences and seminars, for
example, "Electron Glass Transition in Lightly Doped
Semiconductors" at "4th International Conference
on Hopping and Related Phenomena", August 1991, Marburg, Germany
; "Quantitative Characterization of Impurities in III-V
Semiconductors" at "International Conference on Cond. Mat.
Physics and Applications", April. 1992, Bahrain; "Electron
Glass Transition" at the International Workshop "Frontiers
in the Physics of Complex Systems", March 2001, Tel Aviv,
Israel.
Selected papers:
- S.D. Baranovskii, A.L. Efros, B.L. Gelmont,
B.I. Shklovskii "Coulomb Gap in Disordered
Systems", Solid State Communication. 27, 1 (1978).
- S.D. Baranovskii, A.L. Efros, B.L. Gelmont,
B.I. Shklovskii "Coulomb Gap in Disordered Systems:
Computer Simulation", J. Phys. C: Solid State Phys. 12,
1023 (1979).
- S.D. Baranovskii and A.A. Uzakov "On the High-Frequency
Impurity Hopping Conductivity",
Solid State Commun. 36, 829 (1980).
- S.D. Baranovskii, A.L. Efros, B.I. Shklovskii
"Elementary Excitations in Disordered Systems with
Localized Electrons", Sov. Phys. JETP 51, 199 (1980).
- S.D. Baranovskii and A.A. Uzakov "Interimpurity
Absorption of Infrared Radiation in Lightly Doped
Semiconductors", Sov. Phys. Semicond. 16, 1026 (1982).
- S.D. Baranovskii, A.A. Uzakov, A.L. Efros
"Thermodynamic Properties of Impurity Band
Electrons", Sov. Phys. JETP 56, 422 (1982).
- S.D. Baranovskii, A.L. Efros, B.I. Shklovskii
"Screening in a System with Localized Electrons",
Sov. Phys. JETP 60, 1031 (1984).
- S.D. Baranovskii et al. "Temperature Dependence of
the Lineshape of 1s®2p
Photothermal Ionization of Donors in GaAs",
Sov. Phys. JETP Lett. 46, 510 (1987).
- S.D. Baranovskii et al. "Quadrupole Line-Broadening
for Hydrogen-Like Impurities in Lightly Doped Compensated
Semiconductors", Sov. Phys. Semicond. 22, 1002 (1988).
- S.D. Baranovskii and B.I. Shklovskii "Temperature
Dependence of the Line Profile of Photoionization of Impurities
in Lightly Doped Weakly Compensated Semiconductors",
Sov. Phys. Semicond. 23, 122 (1989).
- S.D. Baranovskii "Theoretical Basis for Quantitative
Characterization of Impurities in n-type III-V Semiconductors
by Photoelectromagnetic Spectroscopy", Appl. Surface
Science 50, 218 (1991).
- S.D. Baranovskii et al. "Electron Glass Transition in
Lightly Doped Semiconductors",
Philos. Mag. B 65, 685 (1992); J. Appl. Phys. 71, 2452 (1992).
- S.D. Baranovskii and P. Thomas, Comment on "Phase
Transition of an Exciton System in GaAs Coupled Quantum
Wells" and "Fermi-Dirac Distribution of Excitons in
Coupled Quantum Wells", Phys. Rev. Lett. 69, 993 (1992).
- S.D. Baranovskii et al. "Spectroscopic Determination
of the Compensation Degree and Impurity Concentration in
High-Purity GaAs", in "Best of Soviet Semiconductor
Physics and Technology", ed. M. Levinstein and M. Shur
(World Scientific, Singapore, 1995) p.71.
- I.S. Shlimak, ..., S.D. Baranovskii et al.
"Temperature-Induced Smearing of the Coulomb Gap by
Hopping Electrons", Phys. Rev. Lett. 75, 4764 (1995).
- S.D. Baranovskii et al. "On the Potential Fluctuations
in Amorphous Silicon", J. Non-Cryst. Solids 190, 117 (1995).
- J.E. Colub, S.D. Baranovskii, P.Thomas, "Role of
Interactions in the Energy-Loss Hopping and Recombination of
Two-Dimensional Electrons and Holes", Phys. Rev. B 55,
4575 (1997).
-
Optical and transport properties of semiconductor glasses
Theory of the transport and optical properties of such materials has
been developed with taking into account the multiphonon nature of
electronic transitions. A comprehensive review article on this
topic was published.
Selected papers:
- Review article: S.D. Baranovskii and V.G. Karpov "Localized
Electron States in Semiconductor Glasses", Sov. Phys. Semicond.
21, 1 (1987).
-
S.D.Baranovskii and V.G. Karpov "Thermal Quenching of
Photoluminescence in Chalcogenide Glasses", Sov. Phys. Semicond.
18, 828 (1984).
-
M. Babacheva, S.D. Baranovskii et al. "Influence of Photostructural
Transformations in As2S3 Films on Urbach
Absorption Edge", Sov. Phys. Solid State 26, 1331 (1984).
-
S.D.Baranovskii et al. "Ambipolar Photoconductivity in Glasses
Ge-Pb-S", Sov. Phys. Semicond. 18, 633 (1984).
-
S.D. Baranovskii and V.G. Karpov "Probability of Capture and
Dispersive Transport in Non-Crystalline Semiconductors", Sov.
Phys. Semicond. 19, 336 (1985).
-
S. D. Baranovskii and E.A. Lebedev "Localized States Limiting Drift
Mobility in Amorphous Se-Containing S, Te and As", Sov. Phys.
Semicond. 19, 635 (1985).
-
S.D. Baranovskii, B.L. Gelmont, K.D. Tsendin "Compensation Level in
Modified Semiconductor Glasses", Sov. Phys. Semicond. 20, 1137
(1986); J. Non-Cryst. Solids 97-98, 487 (1987).
-
S.D. Baranovskii and V.G. Karpov "Kinetics of Photoluminescence Decay
in Semiconductor Glasses", Sov. Phys. Semicond. 20, 192 (1986).
-
S.D. Baranovskii and V.G. Karpov "Multiphonon Hopping Conductivity",
Sov. Phys. Semicond. 20, 1137 (1986).
-
S.D. Baranovskii and V.G. Karpov "Frequency Dependence of the
Capacitance of Metal-Insulator Semiconductor Structures on the Basis
of Non-Crystalline Materials", Sov. Phys. Semicond. 21, 1280
(1987).
-
S.D. Baranovskii and M. Silver "The Effect of Long-Range Coulomb
Potential on the Electronic Structure of Localized States in
Homogeneous Intrinsic Amorphous Semiconductors", Philos. Mag.
Lett. 61, 77 (1990).
-
S.D. Baranovskii, V.K. Tikhomirov, G.J. Adriaenssens "Evidence for a
Temperature Dependence of the Intrinsic Dipoles in Chalcogenide
Glasses", Phil. Mag. Lett. 77, 295 (1998).
- Theory of electronic transport and photoluminescence in
amorphous semiconductors (bulk materials and quantum wells).
Various
regimes were considered with respect to the temperature conditions
(low, intermediate and high temperatures), recombination mechanisms
(radiative and non-radiative), electric fields (linear transport at
low fields and non-linear transport at high fields) etc.. Special
attention has been given to the development of the theoretical basis
for various experimental techniques, such as the time-resolved and
frequency-resolved spectroscopy, the thermally stimulated currents,
the time-of-flight technique. Basic ideas are applicable to the
description of electronic transport in various disordered
semiconductors, for example, in microcrystalline silicon and in
porous silicon.
Numerous invited talks were given at conferences and seminars, for
example, "Low-Temperature Transport in Disordered Materials"
at "Chelsea Meeting on Disordered Semiconductors", December
1990, London, U.K.; "Photoluminescence in Amorphous Silicon"
at "International Workshop on Light-Emitting Silicon", July
1992, Munich, Germany; "Nonlinear Hopping Transport in Band
Tails" at "16th International Conference on
Amorphous Semiconductors", September 1995, Kobe, Japan;
"Thermally Stimulated Currents at Low Temperatures" at "7th
International Conference on Hopping and Related Phenomena",
August 1997, Rackeve, Hungary.
Selected papers:
- S.D. Baranovskii, E.L. Ivchenko, B.I. Shklovskii "A Novel Tunneling
Recombination Regime for Photoexcited Carriers in Amorphous
Semiconductors", Sov. Phys. JETP 65,1260 (1987).
-
S.D. Baranovskii, V.G. Karpov, B.I. Shklovskii "Theory of
Non-Radiative Recombination in Amorphous Semiconductors", J.
Non-Cryst. Solids. 97-98, 487 (1987); Sov. Phys. JETP 67, 538 (1988).
-
S.D. Baranovskii et al. "Photoluminescence and Photoconductivity in
Amorphous Semiconductors at Low Temperatures", Sov. Phys. JETP
69, 775 (1989).
- B.I. Shklovskii, H. Fritzsche, S.D. Baranovskii "Electronic Transport
and Recombination in Amorphous Semiconductors at Low Temperatures",
Phys. Rev. Lett. 62, 2989 (1989).
- M.E. Raikh, S.D. Baranovskii, B.I. Shklovskii "Dimensional
Quantization in a-Si:H Quantum Well Structures: the Alloy Model",
Phys. Rev. B 41, 7701 (1990).
- S.D. Baranovskii et al. "Low-Temperature Photoconductivity of Doped
Amorphous Semiconductors", Solid State Communications 86, 549
(1993).
- S.D. Baranovskii et al. "Effective Temperature for Electros in Band
Tails", J. Non-Cryst. Solids. 164-166 (1993).
- G.J. Adriaenssens, S.D. Baranovskii et al. "Photoconductivity
Response Time in Amorphous Semiconductors", Phys. Rev. B 51,
9661 (1995).
- B. Cleve,
B. Hartenstein, S.D. Baranovskii et al. "High-Field Hopping
Transport in Band Tails of Disordered Semiconductors", Phys.
Rev. B 51, 16705 (1995).
- S.D. Baranovskii et al. "On the Description of Hopping Energy
Relaxation and Transport in Disordered Systems", J. Non-Cryst.
Solids 198-200, 222 (1996).
- S.D. Baranovskii and P. Thomas "Nonlinear Hopping Transport in Band
Tails", J. Non-Cryst. Solids 198-200, 140 (1996).
- S.D. Baranovskii et al. "Thermally Stimulated Conductivity in
Disordered Semiconductors at Low Temperatures", Phys. Rev. B 55,
16226 (1997).
- J.-H. Zhou, S.D. Baranoskii, S. Yamasaki et al. "On the Transport
Properties of Microcrystalline Silicon at Low Temperatures",
Phys. Stat. Solidi (b) 205, 147 (1998).
- S.D. Baranovskii, Comment on "Absence of Carrier Hopping in Porous
Silicon", Phys. Rev. Lett. 81, 3804 (1998).
-
General description of diffusion and drift processes in the
fluctuation regime
In particular, a relation between the mobility and diffusivity for
hopping charge carriers in the non-equilibrium regime has been
derived. The latter replaces the well-known Einstein relation valid
for equilibrium transport.
Numerous invited talks were given at conferences and seminars,
for example, "Einstein Relation for Hoping Electrons"
at "9h International Workshop of Condensed Matter
Physics", September 1996, Varna, Bulgaria.
Selected papers:
- S.D. Baranovskii et al. "Einstein Relation for Hopping
Electrons", J. Non-Cryst. Solids 198-200, 214 (1996).
-
S.D. Baranovskii et al. "Long-Time Asymptotics in the
Diffusion-Controlled A+B®0
Reaction with Hopping Energy Relaxation", J. Chem. Phys. 106,
3157 (1997).
-
S.D. Baranovskii et al. "On the Einstein Relation for Hopping
Electrons", Physica Status Solidi (b) 205, 91 (1998).
-
S.D. Baranovskii et al. " On the Einstein Relation for Hopping
Electrons", J. Non-Cryst. Solids 227-230, 158 (1998).
-
Thermodynamic condensation theory of supersaturated vapors.
In particular, a
simple and general mechanism has been suggested for puzzling so far
effect of photo-induced condensation. The latter was observed
experimentally in a variety of species, though it has never been
explained before on a general basis.
Selected papers:
-
S.D. Baranovskii et al. "On the Time Decay of the Photoinduced
Condensation in Supersaturated Vapors", J. Chem. Phys. 103, 7796
(1995).
-
H. Uchtmann, R. Dettmer, S.D. Baranovskii, F. Hensel "Potoinduced
Nucleation in Supersaturated Mercury Vapor", J. Chem. Phys. 108,
9775 (1998).
-
H. Uchtmann, S. Yu. Kazitsyna, S.D. Baranovskii, F. Hensel
"Light-Induced Nucleation and Optical Absorption in Cesium
Vapor", J. Chem. Phys. 113, 4171 (2000).
-
Transport of ions in dielectric glasses.
A comprehensive theory has been developed that provides natural
explanation for many effects, which are still often called "a
challenge to science of 21st century". One of these
effects is an enormous nonlinearity of the conductivity with respect
to the concentration of ions. For example, changing the latter by a
factor of two leads to the changing of the conductivity by many
orders of magnitude. Another puzzling and not yet explained effect
known since 1925 is the so-called mixed-cation effect: gradual
replacing of well-conducting cations in a glass matrix by not worse
conducting cations leads to an
enormous decrease of the conductivity. It appears possible to show
that these effects as well as many other puzzling effects can be well
accounted for by a routine percolation approach using a well- known
structural model for ionic glasses.
Numerous invited talks were given at conferences and seminars, for
example, "Transport Mechanism in Ionic Glasses" at "9h
International Conference on Hopping and Related Phenomena",
September 1999, Murcia, Spain.
Selected papers:
- S.D. Baranovskii and H. Cordes "On the Transport Mechanism in Ionic
Glasses", J. Chem. Phys. 111, 7546 (1999).
-
H. Cordes and S.D. Baranovskii "On the Conduction Mechanism in Ionic
Glasses", Physica Status Solidi (b) 218, 133 (2000).
-
Charge carrier transport in organic disordered solids
A comprehensive theory has been developed that provides a natural
explanation for experimentally observed dependencies of carrier
mobility on temperature, electric field, concentration of localized
states, localization length etc. in the conjugated polymers,
molecularly doped polymers and organic glasses. Combined with
experimental data, the theory gives rather precise estimates for
material parameters, such as the energy spread of localized states,
their concentration and the localization length.
Numerous invited talks were given at conferences and seminars, for
example, "Transport Mechanism in Disordered Organic Solids"
at "3rd International Conference on Science and
Technology of Synthetic Metals", July 2000, Bad Gastein,
Austria.
Selected papers:
- S.D. Baranovskii et al. "On the Description of Charge Carrier
Transport in Disordered Organic Solids", Phys. Rev. B 62, 7934
(2000).
-
H. Cordes, S.D. Baranovskii et al. "One-Dimensional Hopping Transport in
Disordered Organic Solids. I. Analytic Theory", Phys. Rev. B
63, No.9 (2001).
-
K. Kohary,
H. Cordes, S.D. Baranovskii et al. "One-Dimensional Hopping
Transport in Disordered Organic Solids. II. Monte Carlo Simulations",
Phys. Rev. B 63, No.9 (2001).